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Stretching Frequency and Force Constant of the Tungsten‐Carbon Triple Bond
Author(s) -
Fischer Ernst Otto,
Dao Nguyen Quy,
Wagner Wolfgang Rainer
Publication year - 1978
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197800501
Subject(s) - carbyne , triple bond , raman spectroscopy , force constant , tungsten , materials science , bond , bond order , carbon fibers , bond length , chemistry , crystallography , composite material , molecule , double bond , polymer chemistry , physics , metallurgy , organic chemistry , quantum mechanics , composite number , crystal structure , carbene , catalysis , finance , economics
The IR and Raman spectra of the carbyne complexes (1) to (4) have been analyzed in order to gain a further insight into the nature of the metal‐carbon bond. The results provide independent proof of a triple bond.