Addition Compounds with Polymeric Chromium( II )‐Schiff Base Complexes | Zendy

Sawodny Wolfgang | Zendy; Riederer Manfred | Zendy

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Addition Compounds with Polymeric Chromium( II )‐Schiff Base Complexes

Author(s) -

Sawodny Wolfgang,

Riederer Manfred

Publication year - 1977

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197708591

Subject(s) - chromium , schiff base , cyclohexane , chemistry , molecule , intercalation (chemistry) , pyridine , palladium , platinum , polymer chemistry , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis

Highly stable complexes of Schiff bases and chromium( II ), palladium( II ), or platinum( II ) have now been synthesized. Such a complex is the Cr 2+ compound (2a) . It can form addition compounds with molecules such as CH 3 OH, pyridine, or cyclohexane. Complexes of type (2) containing Pd 2+ or Pt 2+ and R = e.g. (CH 2 ) x , x = 2–8, 10, 12 are accessible from (1) and K 2 PdCl 4 or K 2 PtCl 4 in DMF/NaOAc. They can also intercalate organic molecules.

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