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Oxidation and Reduction of Methylthio‐Substituted π‐Systems and the Electron Distribution in Their Radical Ions
Author(s) -
Bock Hans,
Brähler Georg
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197708551
Subject(s) - ion , molecule , radical ion , chemistry , one electron reduction , electron , reduction (mathematics) , photochemistry , computational chemistry , electrochemistry , organic chemistry , physics , electrode , nuclear physics , mathematics , geometry
The radical anion M •⊖ and the radical cation M •⊕ have so far both been detected for few molecules M. Methylthio‐substituted π‐systems such as (1) represent a new type of such molecules. Comparison of the calculated charge distributions for M, M •⊖ , and M •⊕ with the experimental spin densities ρ ⊖ and ρ ⊕ is of topical interest.
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