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Functional Vinyl Carbanions—Deprotonation of β‐(1‐Pyrrolidinyl)acrylonitrile
Author(s) -
Schmidt Richard R.,
Talbiersky Jörg
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197708531
Subject(s) - carbanion , electrophile , acrylonitrile , deprotonation , chemistry , socrates , polymer chemistry , organic chemistry , catalysis , polymer , philosophy , ion , epistemology , copolymer
Selective electrophilic reactions at the α‐ or β‐position of β‐(1‐pyrrolidinyl)acrylonitrile (1) , NR 2 = pyrrolidinyl, can be accomplished in many cases by lithiation of (1) at −113 or −76°C and subsequent reaction with the electrophile.
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