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The Selectivity of Chemical Reactions Disguised by Diffusion. Part I: Chemical Selectivity Disguised by Mixing
Author(s) -
Rys Paul
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197708073
Subject(s) - mixing (physics) , selectivity , diffusion , chemical reaction , product distribution , chemistry , product (mathematics) , computer science , organic chemistry , thermodynamics , mathematics , physics , catalysis , quantum mechanics , geometry
A mixing‐reaction model (MIRE) is used to develop criteria, readily accessible by experiment, which permit the chemist to decide whether and when mixing effects influence the product distribution in competitive consecutive or parallel reactions. The validity of these criteria is demonstrated by comparison of prediction and experiment in the examples used.