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A Novel Transformation of Diphenylcyclopropenone: Double Bond Cleavage in the Reaction with Platinum Complexes
Author(s) -
Carrol W. Eamon,
Green Michael,
Howard Judith A. K.,
Pfeffer Michel,
Stone F. Gordon A.
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197707931
Subject(s) - platinum , cleavage (geology) , chemistry , double bond , ring (chemistry) , transition metal , bond cleavage , crystallography , stereochemistry , bridging (networking) , polymer chemistry , materials science , catalysis , organic chemistry , computer science , fracture (geology) , composite material , computer network
The novel dinuclear platinum complex (1) is doubly bridged by ring‐opened diphenylcyclopropenone. Neither the cleavage of the CC double bond of a small ring by a transition metal complex nor bridging ligands of this kind (X‐ray structure analysis) were formerly known.