New Aliphatic Thioacylating Reagents; Preparation of  tert ‐Butyl Esters of Aliphatic Dithiocarboxylic Acids  via  Bis(thioacyl) Sulfide | Zendy

Kato Shinzi | Zendy; Takagi Takashi | Zendy; Katada Tomonori | Zendy; Mizuta Masateru | Zendy

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New Aliphatic Thioacylating Reagents; Preparation of tert ‐Butyl Esters of Aliphatic Dithiocarboxylic Acids via Bis(thioacyl) Sulfide

Author(s) -

Kato Shinzi,

Takagi Takashi,

Katada Tomonori,

Mizuta Masateru

Publication year - 1977

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197707861

Subject(s) - reagent , chemistry , sulfide , isopropyl , steric effects , organic chemistry , derivative (finance) , medicinal chemistry , economics , financial economics

Aliphatic bis(thioacyl) sulfides (1) , now obtainable by routes A and B, are versatile reagents. For example, they can be used to prepare dithio esters, also of sterically hindered alcohols. (1) , R = isopropyl, dimerizes to the dithietane derivative (2) , which like (1) is possibly an intermediate of the cyclization of dithio acids to hexathiaadamantanes.

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