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Co 5 (CO) 11 (PR 2 ) 3 , A Novel Type of Pentanuclear Cluster
Author(s) -
Keller Egbert,
Vahrenkamp Heinrich
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197707311
Subject(s) - cluster (spacecraft) , crystallography , trigonal crystal system , valence (chemistry) , chemistry , physics , computer science , crystal structure , quantum mechanics , programming language
Edge‐bridged trigonal pyramids of Co atoms make up the novel pentanuclear cluster (1) (11 CO and 6 methyl groups have been omitted). The valence bond notation with resonance formulas provides an acceptable picture of the bonding in this system.