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Diastereoselective Synthesis of the Aporphine Alkaloid (+)‐Cataline. Hydroxylation with Vanadium( V ) Trifluoride Oxide
Author(s) -
Hartenstein Johannes,
Satzinger Gerhard
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197707301
Subject(s) - aporphine , alkaloid , chemistry , vanadium , hydroxylation , stereochemistry , organic chemistry , enzyme
Simplicity and stereospecificity characterize a one‐step synthesis of (±)‐cataline (3) from (±)‐laudanosine (1) (RCH 3 O, R′CH 3 ). The product is accompanied by small amounts of (±)‐glaucine (2) .
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