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(3—6‐η‐Tricyclo [6.2.2.0 2,7 ] dodeca‐3,5,9,11‐tetraene)‐tricarbonyliron, a Stable Transition Metal Complex of “ o , p ′‐Dibenzene”
Author(s) -
Grimme Wolfram,
Schneider Ernst
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197707171
Subject(s) - dimer , chemistry , benzene , oxidizing agent , cleavage (geology) , transition metal , stereochemistry , medicinal chemistry , catalysis , organic chemistry , materials science , fracture (geology) , composite material
The Diels‐Alder dimer of benzene has now been synthesized in the form of the stable tricarbonyliron complex (1) . On liberation by oxidizing cleavage, the dimer immediatedly decomposes to benzene.
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