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Thermal Rearrangement of Silylmethyl Acetates
Author(s) -
Reetz Manfred T.,
Greif Norbert
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197707121
Subject(s) - ylide , intramolecular force , chemistry , sigmatropic reaction , ionic bonding , carroll rearrangement , cope rearrangement , mechanism (biology) , photochemistry , medicinal chemistry , stereochemistry , organic chemistry , philosophy , ion , epistemology
The inverted ylide (2) is postulated as an intermediate of the intramolecular rearrangement of silylmethyl acctates (1) , R 3 CH 3 or CF 3 . A concerted dyotropic or a two‐step radical process are ruled out, and an ionic mechanism is unlikely.
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