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Bis[trimethylphosphorio(‐onio)]methanide, A “Semi‐Ylidic” Ligand in Transition Metal Complexes
Author(s) -
Kreissl Fritz R.,
Eberl Karl,
Stückler Peter
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197706541
Subject(s) - ligand (biochemistry) , rhenium , transition metal , metal , coupling (piping) , chemistry , physics , materials science , inorganic chemistry , receptor , organic chemistry , metallurgy , biochemistry , catalysis
The novel rhenium complex (1) has now been isolated and characterized as the first transition metal complex having a semi‐ylidic ligand. The PCH 3 groups are equivalent ( 31 P‐ 1 H coupling).