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Synthesis and Reactivity of Hetero Dinuclear Complexes Containing a Mn—Co Bond
Author(s) -
Leonhard Konrad,
Werner Helmut
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197706491
Subject(s) - reactivity (psychology) , chemistry , cleavage (geology) , manganese , bridging (networking) , bond cleavage , crystallography , stereochemistry , catalysis , materials science , organic chemistry , computer science , medicine , computer network , alternative medicine , pathology , fracture (geology) , composite material
The selective cleavage of the Mn(μ‐CO) 2 Co bridging fragment in complex (1) is the first one of its kind. With L = PMe 3 or C 2 Ph 2 the Mn compound MeC 5 H 4 Mn(CO) 3 is obtained in either case, together with the Co compound C 5 H 5 Co(PMe 3 ) 2 or C 5 H 5 Co(PMe 3 )(C 2 Ph 2 ).