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Reactivity of η 5 ‐Indenylrhodium ( I ) Complexes; Cyclocotrimerization of Alkynes with Alkenes
Author(s) -
Caddy Peter,
Green Michael,
O'Brien Edmund,
Smart Lesley E.,
Woodward Peter
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197706481
Subject(s) - reactivity (psychology) , chemistry , alkyne , medicinal chemistry , stereochemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology
Indenyl‐and cyclopentadienylrhodium(I) complexes have somewhat different properties. Observations on indenyl complexes (ligands not shown) suggest the following reaction course for cyclocotrimerization of alkynes with alkenes:
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