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Diphosphinomethanide/Phosphoniumbismethylide: A Novel Ligand Combination for Transition Metals
Author(s) -
Schmidbaur Hubert,
Mandl Johann R.
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197706401
Subject(s) - ligand (biochemistry) , transition metal , thermal stability , coordination complex , chemistry , transition (genetics) , metal , combinatorial chemistry , crystallography , materials science , organic chemistry , receptor , biochemistry , catalysis , gene
Novel transition metal complexes such as (1) and (2) contain a combination of the ligand systems (A) and (B) . The new coordination compounds have a notable tendency to formation and high thermal stability.