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Anomalous Nucleophilic Substitution in (Chloromethyl)silane: 1,2‐Hydride Shift
Author(s) -
Schmidbaur Hubert,
ZimmerGasser Beate
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197706392
Subject(s) - silane , silylation , alkyl , substitution (logic) , chemistry , nucleophilic substitution , medicinal chemistry , hydride , nucleophile , polarity (international relations) , organic chemistry , catalysis , computer science , hydrogen , programming language , biochemistry , cell
H 3 SiCH 2 Cl (1) and its analog H 3 CCH 2 Cl differ in the polarity of the CCl bond. The first reactions of (1) have now been found which proceed differently from those of the “true” alkyl compound. (RCH 3 or C 2 H 5 ; repeated silylation finally affords R 3 PC(SiH 2 CH 3 ) 2 ).
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