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Hydrogenolysis of Trisubstituted Dichlorophosphoranes—A New Method for Deoxygenation of Oxophosphoranes
Author(s) -
Masaki Mitsuo,
Kakeya Noboru
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197705522
Subject(s) - deoxygenation , hydrogenolysis , proposition , key (lock) , reduction (mathematics) , chemistry , process (computing) , process engineering , computer science , organic chemistry , catalysis , mathematics , engineering , philosophy , computer security , epistemology , programming language , geometry
Regeneration of R 3 P from R 3 PO was formerly an uneconomic proposition. The key step of a new process consists in reduction of dichlorophosphorane with hydrogen under pressure.