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Synthesis and Structure Determination of a 1,4‐Dialuminacyclohexadiene
Author(s) -
Hoberg Heinz,
Gotor Vicente,
Milchereit Armin,
Krüger Carl,
Sekutowski Janine C.
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197705391
Subject(s) - metalation , electrophile , chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis
The cyclic organoaluminum compound (1) is formed under mild conditions from the ate complex Na 2 [ cis ‐Ph(Et 3 Al)CC(AlEt 3 )Ph] and electrophiles. X‐ray structure analysis showed there to be no bond between the two Al atoms. Compound (1) undergoes ortho ‐metalation of the four phenyl groups on reaction with Li.