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Reaction of Arsonium Ylides with Carbonyl Compounds—Effect of Substituents at Arsenic
Author(s) -
Gosney Ian,
Lillie Terence J.,
Lloyd Douglas
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197704871
Subject(s) - arsenic , chemistry , medicinal chemistry , photochemistry , organic chemistry
Alkenes and/or epoxides are formed on reaction of arsonium ylides with aldehydes. The product ratio can be influenced by variation of the substituents. Phosphonium ylides give only alkenes, and sulfonium ylides only epoxides.