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Synthesis and Properties of Tris(trimethylsilyl)aluminum
Author(s) -
Rösch Lutz
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197704801
Subject(s) - trimethylsilyl , thermal decomposition , yield (engineering) , tris , aluminium , decomposition , chemistry , pyrolysis , mineralogy , materials science , organic chemistry , metallurgy , biochemistry
The AlSi compound (1) has now been prepared for the first time in about 90% yield. The thermolysis products of (1) suggest the intermediacy of dimethyl‐silanediyl [(CH 3 ) 2 Si].