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Synthesis and Chemistry of Alkylidenediaziridines
Author(s) -
L'abbé Gerrit,
Yu ChihChou,
Toppet Suzanne
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197704752
Subject(s) - isocyanate , chemistry , cleavage (geology) , bond cleavage , polymer science , polymer chemistry , combinatorial chemistry , organic chemistry , materials science , catalysis , polyurethane , composite material , fracture (geology)
The first alkylidenediaziridines (2) have now been synthesized by the reaction shown below. On heating they rearrange with cleavage of the NN bond; oxazolidinimines are formed with phenyl isocyanate.
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