η‐Cyclopentadienyl(η‐diborolenyl)nickel—A Diamagnetic Nickelocene Analog | Zendy

Siebert Walter | Zendy; Bochmann Manfred | Zendy

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η‐Cyclopentadienyl(η‐diborolenyl)nickel—A Diamagnetic Nickelocene Analog

Author(s) -

Siebert Walter,

Bochmann Manfred

Publication year - 1977

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197704681

Subject(s) - nickelocene , nickel , cyclopentadienyl complex , diamagnetism , chemistry , deprotonation , photochemistry , orange (colour) , inorganic chemistry , polymer chemistry , ion , organic chemistry , physics , catalysis , ferrocene , quantum mechanics , food science , electrode , magnetic field , electrochemistry

The first complex of a deprotonated diborolene has now been synthesized as orange‐red platelets. The electron balance in the sandwich complex can be described by assuming its construction from two aromatic rings (C 5 − , C 3 B 2 3− ) and the Ni d 6 cation.

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