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Phenyl‐[2,2‐dimethyl‐1‐(trimethylsiloxy) propylidene]‐arsane, and Arsane with an Isolated AsC Bond
Author(s) -
Becker Gerd,
Gutekunst Gerhard
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197704631
Subject(s) - double bond , chemistry , trimethylsilyl , bond , medicinal chemistry , stereochemistry , organic chemistry , business , finance
The first open‐chain arsane with an isolated AsC double bond , (2) , has now been prepared by rearrangement of the pivaloylarsane (1) . Compound (1) is obtainable from phenylbis(trimethylsilyl)arsane.