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Synthesis of α,β=Unsaturated Cyclic Ketones by Sensitized Photooxidation of Silyl Enol Ethers
Author(s) -
Friedrich Edgar,
Lutz Werner
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197704132
Subject(s) - enol , silylation , chemistry , organic chemistry , photochemistry , catalysis
Regiospecific introduction of a double bond into ketones has now been achieved under such mild conditions that no racemization occurs at the adjacent chiral center.