Reversible Transition between a [4]Radialene and a Cyclobutadiene by Electron Transfer | Zendy

Horner Michael | Zendy; Hünig Siegfried | Zendy

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Reversible Transition between a [4]Radialene and a Cyclobutadiene by Electron Transfer

Author(s) -

Horner Michael,

Hünig Siegfried

Publication year - 1977

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197704101

Subject(s) - cyclobutadiene , antiaromaticity , character (mathematics) , electron , electron transfer , component (thermodynamics) , chemistry , chemical physics , photochemistry , physics , organic chemistry , thermodynamics , quantum mechanics , mathematics , molecule , geometry , aromaticity

Estimates of the antiaromatic character of a cyclobutadiene from reversible potentials have now been accomplished for the first time for (1) . (1) is a component of one of the few π‐systems that can exist in five oxidation states connected by four reversible one‐electron transfers.

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