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μ‐Thiadiborolene‐bis(η‐thiadiborolenecobalt)—A “Homogeneous” Triple‐Decker Sandwich with Three Heterocyclic Ligands
Author(s) -
Siebert Walter,
Rothermel Wilfried
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197703331
Subject(s) - homogeneous , cobalt , crystallography , valence (chemistry) , chemistry , electron , valence electron , stereochemistry , inorganic chemistry , physics , organic chemistry , thermodynamics , quantum mechanics
Two cobalt atoms and three thiadiborolene rings (1) make up a “homogeneous” triple‐decker sandwich complex which has now been synthesized. The 30 valence electrons formally arise from two Co d 6 cations and three thiadiborolene dianions.