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“Supersandwich”‐Type Trinuclear Complexes with a Spiro Center
Author(s) -
Werner Helmut,
Khac Tri Ngo
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197703241
Subject(s) - center (category theory) , type (biology) , chemistry , atom (system on chip) , ion , crystallography , metal , mass spectrum , stereochemistry , organic chemistry , geology , computer science , embedded system , paleontology
A new type of “supersandwich” complex has the central metal atom acting as spiro center. (1) , MCo, RCH 3 , and (2) , MZn, RCH 3 , are stable compounds; the Ni analog can only be detected in the mass spectrum as the molecular ion.