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N ‐Acyl Isocyanides
Author(s) -
Höfle Gerhard,
Lange Bernd
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197702621
Subject(s) - isocyanide , acylation , cycloaddition , chemistry , medicinal chemistry , organic chemistry , catalysis
The first acyl isocyanides have now become available. The pronounced carbonyl‐activation of benzoyl isocyanide (1) is manifested, e.g. , in the acylation of ynamines; in contrast, (1) undergoes cycloaddition with acetylenedicarboxylates.