Premium
Diastereoisomers with Differing Bond Lengths: Structure Analysis of the Diastereomeric Forms of μ‐(1,2‐Dichloro‐1,2‐diphenyldiphosphane)bis(pentacarbonylchromium)
Author(s) -
Huttner Gottfried,
Friedrich Peter,
Willenberg Heinrich,
Müller HansDieter
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197702601
Subject(s) - diastereomer , steric effects , chemistry , stereochemistry
The central bonds in the diastereomeric complexes (1) and (2) are of different length. This efect, described here for the first time, is attributed to steric interactions between the substituents.