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Decarboxylative Dehydration of β‐Hydroxycarboxylic Acids by Redox Condensation: A Novel Olefin Synthesis
Author(s) -
Mulzer Johann,
Brüntrup Gisela
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197702551
Subject(s) - dehydration , wittig reaction , adduct , chemistry , olefin fiber , organic chemistry , condensation , redox , sequence (biology) , diethyl azodicarboxylate , condensation reaction , catalysis , biochemistry , physics , thermodynamics , triphenylphosphine
An alternative to the Wittig reaction is provide by the reaction sequence (A)+(B). The adduct of PPh 3 and diethyl azodicarboxylate is suitable for use as X.
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