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A Novel 3z‐2e Bond System
Author(s) -
Grobe Joseph,
Martin Roland,
Möller Uwe
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197702481
Subject(s) - palladium , atomic orbital , planar , bond , unit (ring theory) , crystallography , chemistry , electron , physics , atomic physics , materials science , computer science , mathematics , quantum mechanics , organic chemistry , business , computer graphics (images) , catalysis , mathematics education , finance
One‐electron bonds between Pd and Si are formally present in the complex (1) ; the bonding is interpreted assuming that the 4dx 2 ‐y 2 , 5s, 5px, and 5py orbitals of palladium participate in the planar PdCl 2 P 2 unit.
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