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Selective Monofunctionalization of Non‐Conjugated Dienes by Nitrogen Dioxide/Iodine Monoaddition
Author(s) -
Jäger Volker,
Günther Hans Jürgen
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197702461
Subject(s) - nitrogen dioxide , stoichiometry , yield (engineering) , iodine , conjugated system , nitrogen , chemistry , organic chemistry , medicinal chemistry , materials science , polymer , metallurgy
Unsymmetrical monoadducts (2) of symmetrical 1,5‐, 1,6‐, or 1,7‐dienes (1) have been obtained by reaction with stoichiometric amounts of N 2 O 4 in the presence of I 2 . The bisadducts (3) are formed in <5% yield.