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Acceptor Function of η 2 ‐Bonded CS 2 Ligands
Author(s) -
Herberhold Max,
SüssFink Margot
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701941
Subject(s) - hexamethylbenzene , mesitylene , chemistry , acceptor , nmr spectra database , spectral line , metal , crystallography , medicinal chemistry , stereochemistry , inorganic chemistry , physics , organic chemistry , toluene , benzene , condensed matter physics , astronomy
Withdrawal of charge from a central metal is accomplished better by η 2 ‐bonded CS 2 than by CO. This follows from the IR and 1 H‐NMR spectra of complexes of type (1) (L = CO or PMe 3 ), (2) , and (3) (ar = hexamethylbenzene or mesitylene).
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