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Intramolecular Mobility in CS 2 Complexes of Manganese
Author(s) -
Herberhold Max,
SüssFink Margot,
Kreiter Cornelius G.
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701931
Subject(s) - intramolecular force , manganese , chemistry , molecule , bridge (graph theory) , spectral line , crystallography , stereochemistry , physics , organic chemistry , medicine , astronomy
CS 2 is η 2 coordinated or serves as a novel bridge in the complexes (1) and (2) , as deduced from temperature‐dependent 1 H‐NMR spectra. In dissolved (1) CS 2 undergoes hindered motion; (2) is a fluxional molecule.