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Synthesis and Stereochemistry of Strained Naphthalenophanes
Author(s) -
Bieber Wolfgang,
Vögtle Fritz
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701751
Subject(s) - bracketing (phenomenology) , phenylene , face (sociological concept) , stereochemistry , chemistry , organic chemistry , philosophy , polymer , epistemology , linguistics
Parallel and othogonal π systems are both present in the naphthalenophane (2) synthesized from (1) , R = H, via (1) , R = Br. The effect of bracketing can be studied in isolation for (1) and (2) since the two phenylene rings are already in a “face‐to‐face” arrangement in (1) .