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The Reaction of Olefins with Silane and Carbon Monoxide Catalyzed by Co 2 (CO) 8
Author(s) -
Seki Yoshio,
Hidaka Akihiko,
Murai Shinji,
Sonoda Noboru
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701741
Subject(s) - silanes , silane , silylation , hydroformylation , enol , carbon monoxide , catalysis , chemistry , organic chemistry , rhodium
Enol silyl ethers of type (3) are formed from olefins, CO, and silanes such as (1) in the presence of Co 2 (CO) 8 . Products (2) expected by analogy with hydroformylation do not occur.