Premium
Isolation of Halohydroborates of Type [B 10 H 10 − n X n ] 2−
Author(s) -
Bührens KlausGeorg,
Preetz Wilhelm
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701731
Subject(s) - bromine , iodine , chlorine , tetramethylammonium , chemistry , type (biology) , halogen , analytical chemistry (journal) , ion , chromatography , organic chemistry , ecology , alkyl , biology
The hydrogen atoms of the hydrodecaborate ion (1) can be successively replaced by chlorine, bromine, or iodine. All halohydroborates of type (2) have now been detected by electrophoretic separation; many of them could be isolated pure as tetramethylammonium salts.