Synthesis and Absolute Configuration of Enantiomerically Pure D 3 ‐Trishomocubanes(Pentacyclo [6.3.0.0 2,6 .0 3,10 .0 5,9 ] undecane) and Trishomocubanones | Zendy

Helmchen Günter | Zendy; Staiger Gerhard | Zendy

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Synthesis and Absolute Configuration of Enantiomerically Pure D 3 ‐Trishomocubanes(Pentacyclo [6.3.0.0 2,6 .0 3,10 .0 5,9 ] undecane) and Trishomocubanones

Author(s) -

Helmchen Günter,

Staiger Gerhard

Publication year - 1977

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.197701161

Subject(s) - undecane , absolute configuration , molecule , chiral symmetry , symmetry (geometry) , physics , chemistry , crystallography , stereochemistry , organic chemistry , nuclear physics , geometry , mathematics , quark

Rigid chiral hydrocarbons such as (1) and (2) are of interest as test cases for chiroptical theories. (−)‐Trishomocubane (1) and (+)‐trishomocubane (2) , which have now been obtained enantiomerically pure, are apparently the smallest stable organic molecules of point symmetry D 3 .

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