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Synthesis of Cyclodepsipeptides by Cyclooligomerization
Author(s) -
Rothe Manfred,
Kreiss Wolfgang
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701132
Subject(s) - depsipeptide , valinomycin , chemistry , stereochemistry , organic chemistry , potassium
The antibiotic valinomycin is a cyclic depsipeptide of formula (2), n =3. All cyclodepsipeptides (2) can be prepared by cyclooligomerization of the linear subunits of type (1) in toulene or diethyl phosphite.