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Resolution of a Chiral Olefin by Complexation Chromatography on an Optically Active Rhodium( I ) Complex
Author(s) -
Schurig Volker
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701101
Subject(s) - rhodium , enantiomer , olefin fiber , resolution (logic) , chemistry , optically active , gas chromatography , enantioselective synthesis , chromatography , stereochemistry , organic chemistry , catalysis , artificial intelligence , computer science
Differences in π‐complexation strength of chiral olefins with the rhodium( I ) complex 1 R‐(2) have now been exploited for resolving enantiomers by gas chromatography. Racemic 3‐methylcyclopentene could be resolved quantitatively into the antipodes R ‐ (1) and S ‐ (1).
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