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Isolation and Vibrational Spectra of Bond‐Isomeric Hexakis(thiocyanato‐isothiocyanato) Complexes of Ruthenium( III ) and Osmium( III )
Author(s) -
Schwerdtfeger HansJoachim,
Preetz Wilhelm
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197701081
Subject(s) - ruthenium , osmium , chemistry , ligand (biochemistry) , spectral line , crystallography , stereochemistry , organic chemistry , catalysis , physics , biochemistry , receptor , astronomy
The ambidenate ligand SCN − can bond via S (thiocyanato) or N (isothiocyanato). High voltage electrophoresis resolved the Ru III complex (1) in to four bond isomers, and the Os III complex (2) into three such isomers, which were identified by their vibrational spectra.