Premium
Nucleophilic Substitution of Vinylic Hydrogen Atoms by Carbanions
Author(s) -
Reetz Manfred T.,
Schinzer Dieter
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197700442
Subject(s) - carbanion , elongation , chemistry , sequence (biology) , chain (unit) , nucleophilic substitution , nucleophile , hydrogen , substitution (logic) , terminal (telecommunication) , medicinal chemistry , stereochemistry , organic chemistry , catalysis , materials science , physics , computer science , metallurgy , ultimate tensile strength , programming language , telecommunications , biochemistry , astronomy
Chain elongation of activated terminal olefins can be accomplished by the reaction sequence (1) → (2) → (3). It is also feasible with R = tert ‐butyl, cyclopropyl, and other bulky groups.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom