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The First Oxoferrate( III ) Having a Ring Structure: Na 14 [Fe 6 O 16]
Author(s) -
Brachtel Gerold,
Hoppe Rudolf
Publication year - 1977
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197700431
Subject(s) - crystallography , tetrahedron , ring (chemistry) , oxygen , oxygen atom , ion , chemistry , materials science , molecule , organic chemistry
Twelve‐membered rings with alternate iron and oxygen atoms occur in Na 14 [Fe 6 O 16 ]. Fe is surrounded almost tetrahedrally by O, and along [010] two thirds of the FeO 4 tetrahedra are coupled in the form of a “Dreier‐Doppelkette”.