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The Allylcobalt System
Author(s) -
Bönnemann Helmut,
Grard Charles,
Kopp Werner,
Pump Wichard,
Tanaka Kenjiro,
Wilke Günther
Publication year - 1973
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197309641
Subject(s) - cobalt , stoichiometry , catalysis , homogeneous , chemistry , tris , homogeneous catalysis , polymer chemistry , organic chemistry , physics , biochemistry , thermodynamics
The following report describes the preparation and reactions of organocobalt compounds, especially the thermally unstable tris(π‐allyl)cobalt and cyclooctenylcobalt compounds. The stoichiometric and catalytic transformations of these highly reactive organocobalt systems give an insight into the rôle of cobalt in homogeneous catalysis involving alkenes and alkynes.