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Unusual Substitution in an Arsole Ring
Author(s) -
Märkl Gottfried,
Hauptmann Hagen
Publication year - 1972
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197204411
Subject(s) - citation , art history , library science , art , computer science
CH3 83 170 400 (4.18) -CH,. 7.05 (s) 237 (4.25) aryl-H. 2.06-3.06 (m) The yellow-orange voluminous tert-butyl hypochlorite adducts (3) @=C,H,, CH,C,H,) resemble ( 4 ) in structure but do not decompose to the arsole oxides; however, they disproportionate in solution at room temperature to give (2). In the case of R = CH,C,H, the reaction proceeds further to give the I-chloroarsole (6) directly in 41 % yield.