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Mechanisms of Reactions in the Solid State
Author(s) -
Hardel Kurt
Publication year - 1972
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.197201731
Subject(s) - solid state , reaction rate , rate equation , reaction mechanism , thermodynamics , chemistry , materials science , kinetics , physics , classical mechanics , organic chemistry , catalysis
The reaction of two solid phases X and Y to give a solid compound XY v is taken as an example for the discussion of transport mechanisms and reaction steps. The following methods of investigation are discussed: determination of the rate law, marker experiments, and calculation of the reaction rate. It is pointed out that the investigation of powder reactions leads to problematic conclusions.