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Phosphorus Isocyanates
Author(s) -
Derkatsch G. I.
Publication year - 1969
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196904211
Subject(s) - phosphorus , chemistry , cyanate , halide , thermal decomposition , decomposition , organic chemistry , carbon fibers , inorganic chemistry , materials science , composite number , composite material
Compounds containing the PNCO grouping can be obtained e.g. from phosphorus halides and silver cyanate or esters of N‐chloroiminocarbonic acid and by thermal decomposition of alkoxycarbonylimino‐phosphoranes. The phosphorus (V) isocyanates resemble the “carbon” isocyanates in their chemical properties, whereas the phosphorus (III) isocyanates resemble the phosphorus (III) chlorides. Some of the compounds discussed have insecticidal or cytostatic actions.