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Mechanism of Oxidative Dimerization of Aminobenzenes
Author(s) -
Effenberger F.,
Stohrer W. D.,
Steinbach A.
Publication year - 1969
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196902801
Subject(s) - stuttgart , humanities , chemistry , philosophy
The oxidation was carried out at room temperature with silver salts in dimethylformamide and with tetrahalogenomethanes, cyanogen halides, or halogens in dichloromethane. The salts (31, whose structure has been established by elemental analysis, molecular-weight determinations and 1H-NMR spectra [(3b) in liquid Son: H, = singlet at 7 = 5.03, Hp = singlet at T = 5.671 are obtained in good yields.