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The Catalytic Activity of Transition Metal Compounds in the Liquid‐Phase Oxidation of Hydrocarbons
Author(s) -
Emanuel N. M.,
Maizus Z. K.,
Skibida I. P.
Publication year - 1969
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196900971
Subject(s) - catalysis , transition metal , manganese , cobalt , liquid phase , copper , chemistry , metal , inorganic chemistry , phase (matter) , hydrocarbon , catalytic oxidation , kinetic energy , organic chemistry , thermodynamics , physics , quantum mechanics
The way in which dissolved transition metal compounds affect the liquid‐phase oxidation of hydrocarbons is demonstrated for compounds of cobalt, copper, and manganese. Kinetic investigations on model systems and comparisons with the non‐catalyzed reaction show that the catalysts participate in all the oxidation steps.