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Kinetic Studies on Substitution Reactions of Carbonylmetal Complexes
Author(s) -
Werner H.
Publication year - 1968
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.196809301
Subject(s) - substitution (logic) , steric effects , substitution reaction , chemistry , kinetic energy , computational chemistry , atom (system on chip) , mechanism (biology) , metal , stereochemistry , medicinal chemistry , organic chemistry , physics , computer science , quantum mechanics , embedded system , programming language
Kinetic studies of substitution reactions of carbonylmetals and of carbonylmetal derivatives in which other ligands (n or π donors) besides CO are bound to the metal atom have recently attracted great interest, and the results of these investigations throw a new light on theoretical and preparative problems. The substitution mechanism is determined mainly by steric and electronic factors.